[AR] Re: [AR] Re: [AR] Re: [AR] Re: “Transitioning space propulsion to a nitrous-based industry standard”

  • From: Henry Spencer <hspencer@xxxxxxxxxxxxx>
  • To: Arocket List <arocket@xxxxxxxxxxxxx>
  • Date: Tue, 4 Apr 2023 19:46:16 -0400 (EDT)

On Tue, 4 Apr 2023, Matthew JL wrote:

Why not hydrogen peroxide in monoprop...

For one thing, like most monopropellants, monoprop peroxide gets you into the various hassles of catalyst packs. (Silver screens work well for 85% peroxide, but go much above that concentration and they'll melt; catalysts for 100% peroxide aren't a fully solved problem.)

For long-term in-space use, e.g. in spacecraft orbit control, there is a bigger headache: peroxide does decompose slowly in storage. Careful choice of materials and thorough cleaning can get the rate down low enough that the loss of strength in the peroxide is not a serious issue -- there have been satellites with peroxide propulsion systems. Trouble is, that slow decomposition releases oxygen gas, and that causes pressure buildup in the tanks, and *that's* still serious enough that you can't just live with it. So the tanks have to be vented occasionally, and in microgravity it's rather difficult to separate gas and liquid well enough to vent just the gas. (Unless the satellite is spin-stabilized, in which case careful design can have centrifugal force do the separation for you. The earliest Syncom satellites -- the first spin-stabilized GSO comsats -- had peroxide propulsion.)

And there is considerable superstition about peroxide, partly based on early German and US difficulties with (in hindsight) impure peroxide. Which leads to distrust and suspicion of it, and that can be an obstacle for (e.g.) convincing launcher operators that your peroxide-propelled satellite should be allowed on their precious rocket.

Henry

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