[AR] Re: Hypothetical Lox cooling

  • From: Henry Vanderbilt <hvanderbilt@xxxxxxxxxxxxxx>
  • To: arocket@xxxxxxxxxxxxx
  • Date: Tue, 20 Oct 2020 16:52:07 -0700

I was already assuming Black Arrow avoided peroxide boiling in the cooling passages.  Sorry my question wasn't clear enough: Does anyone have any informed comment on how absolutely necessary, or otherwise, that might be in using h2o2 as a coolant?  As I said, my limited info on the lower stability of peroxide as vapor is anecdotal.

Hmm.  Per Wiki, "The boiling point of H2O2 has been extrapolated as being 150.2 °C (302.4 °F), approximately 50 °C (90 °F) higher than water. In practice, hydrogen peroxide will undergo potentially explosive thermal decomposition if heated to this temperature. It may be safely distilled at lower temperatures under reduced pressure.[7]"

So, possibly there's a practical upper temperature limit even if you do pressurize it to raise the boiling point.

Does anyone _know_?  Thanks in advance...

Henry

On 10/20/2020 12:05 PM, roxanna Mason wrote:

Maybe boiling, at the feed pressure, was avoided. Possible.

K

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On Tue, Oct 20, 2020 at 11:32 AM Henry Vanderbilt <hvanderbilt@xxxxxxxxxxxxxx <mailto:hvanderbilt@xxxxxxxxxxxxxx>> wrote:

    Speaking of possibly exciting hobbies, what happens if you boil
    peroxide in cooling passages?  Is that another one of those things
    one should avoid?

    I gather peroxide cooling worked in Black Arrow, but I have the
    impression from various distillation tales of woe that peroxide
    vapor is much less stable than the liquid. I might guess both that
    preheating the peroxide could help with catalyzing or directly
    combusting it, and also that making sure it stays liquid till then
    is indicated, but those are just guesses.

    Henry

    On 10/20/2020 11:09 AM, Doug Jones wrote:
    A supercritical positive-heat-of-formation oxidizer with oily
    contaminants leached from every step of the distribution chain.
    What could possibly go wrong?

    On Tue, Oct 20, 2020 at 11:04 AM Bruno Berger
    <bruno.berger@xxxxxx <mailto:bruno.berger@xxxxxx>> wrote:

        Am 20.10.2020 um 19:53 schrieb roxanna Mason:
        > Is your fuel even less satisfactory?
        > Perhaps it's a LOx/solid fuel hybrid and you want to cool
        your nozzle.
        >
        Yep, we discussed that at ARIS for cooling the nozzle with
        N2O for their
        5kN hybrid. But N2O probably gets super critical which makes
        me nervous :-(

        Bruno




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