[AR] Re: RP-1 versus ethanol for a student rocket?

  • From: Robert Watzlavick <rocket@xxxxxxxxxxxxxx>
  • To: arocket@xxxxxxxxxxxxx, roxanna Mason <rocketmaster.ken@xxxxxxxxx>
  • Date: Wed, 14 Oct 2020 07:19:43 -0500

One thing I will mention is that for a regen engine using kerosene-type fuels (kerosene, Jet A, RP-1),  you get a benefit from the carbon deposits in the combustion chamber.  There are some plots in NASA SP-125 as it acts as an insulator and reduces the heat transfer to the walls.  Obviously people have made LOX/alcohol work but just thought I'd point it out as it could potentially help your cooling problem converge, especially at smaller thrust levels.  It does make  it harder to clean up afterwards as you have to use an abrasive (scotchbrite) to clean it off.  Other than the potential for coking in the cooling passages on long runs, Jet A, RP-1,  and kerosene should be equivalent.  I've never seen any coking in the cooling passages for runs < 30 seconds.  However, if I was doing a new engine, I would try to make LOX/alcohol work before I went with kerosene, just from the cleanup factor.  I will say one thing though, you know when you've cleaned all the kerosene out as it has a strong smell so maybe it's less likely that you'll leave some fuel in a place where it shouldn't be.

-Bob

On 10/14/20 3:03 AM, roxanna Mason wrote:

Everything combustible ignites easily in a pure oxygen atmosphere and Jet A evaporates surprisingly fast compared to standard kerosene or RP-1.
Ethanol also has a volumetric O/F of unity and easily adjusted by biasing the mass O/F and/or water concentration, also the least toxic of the common alcohols,
there are denaturing formulas that are lower toxicity than others just shop around. You can get a federal permit to make your own ethanol too w/o the $28/gallon excise tax. Also has a somewhat pleasant sweetish odor especially compared to the doctor's office smell of  rubbing isopropyl alcohol, but that is subjective. And there's tons of data on LOx/Ethanol systems being by far the most used alcohol in history as rocket fuel including the V-2 and Redstone ballistic rockets, the X-1 LR-11 manned rocket planes etc. See pic of a single chamber LR-11 captive test of one metric ton thrust, LOx/75% ethanol.
Again it all depends on your requirements and cooling method. Performance wise you can't beat hydrocarbon fuels compared to the alcohols.

K

On Tue, Oct 13, 2020 at 11:41 PM Wyatt Rehder <wyatt.rehder@xxxxxxxxx <mailto:wyatt.rehder@xxxxxxxxx>> wrote:

    I've long maintained that Isopropyl Alcohol is the ideal
    propellant for the amateur liquid rocketeer.
    - Has a close to 1:1 volumetric O:F ratio with LOX which
    simplifies your feed system some (can use similar tank design for
    both)
    - Is easy to obtain at 99% without additives for a low cost (~$500
    for 55 gal last I checked) and no regulation issues
    - Has a high vapor pressure and does not leave a film. So spills
    take care of themselves, doesn't leave residues in your chamber
    after you purge it
    - You can perform your LOX service cleaning with it
    - Has a short bio-persistance, as it readily biodegrades in soil
    and water. So regular spills at your test stand, or a splattered
    rocket isn't going to contaminate the ground soil unlike how
    kerosene can. Granted this isn't a huge issue at amateur scales.

    - Wyatt

    On Tue, Oct 13, 2020 at 10:01 PM Henry Vanderbilt
    <hvanderbilt@xxxxxxxxxxxxxx <mailto:hvanderbilt@xxxxxxxxxxxxxx>>
    wrote:

        Alcohol is easier to source and to work with, yes.  Generally
        easier to get to ignite reliably and combust
        stably/efficiently than kerosene, also considerably easier to
        purge completely from small engine passages between firings
        too.  If you do go with alcohol, you might consider isopropyl
        rather than ethanol - it also can be watered down for extra
        cooling at need, it's generally cheaper, and there are no
        concerns over what they may have "denatured" it with since
        it's not drinkable in the first place.

        One factor to keep in mind in deciding, by the way, is how
        close to the limits of your team's available time, talent, and
        resources will your project push?  (Keep in mind the first
        rule of projects: EVERYTHING takes longer and costs more than
        planned.)  One way to improve the odds your team won't hit a
        wall short of useful results is to simplify wherever possible
        at the start.

        If you do prefer to work with kerosene for the better
        post-graduation industry applicability, one possible
        lower-cost easier-availability substitute for RP-1 is a
        refined-kerosene industrial solvent called Exxsol D40.  It
        does not have RP-1's density, thus is somewhat lower
        performance, but it is non-coking, fully evaporable with no
        residue, is reliably consistent chemically, and you can buy it
        by the drum for a few bucks a gallon.  And it's more or less
        as difficult to get to ignite, combust, and purge cleanly as
        any other kerosene, so you will get plenty of relevant experience.

        FWIW XCOR used LOX/isopropyl for the EZ-Rocket (before my time
        there) and LOX/Exxsol D40 kerosene for the X-Racer.  Never saw
        a trace of coking with it in many, many firings of the
        copper-chamber regen-cooled X-Racer engine, and I was the guy
        who photo-documented the state of the engine components every
        time Mike Laughlin disassembled it to inspect condition and
        service the seals.

        good luck!

        Henry

        On 10/13/2020 9:42 PM, Yucca Works wrote:
        Hello all, my team is considering RP-1 and ethanol right now
        (to be paired with LOX) for our main propellant and I was
        wondering if anyone has any input on which fuel to use given
        some constraints and thoughts to follow. For one, we don't
        have an infinite budget at our disposal so Ethanol becomes
        immediately appealing because it is easy to source, this is
        on top of the fact that Ethanol is not ITAR protected and can
        be mixed with water for "inherent" cooling. What made RP-1
        appealing was the fact that it is used in the industry so
        gaining experience with it seems extremely appealing and, I
        think, would make our work more "useful/notable" but sourcing
        RP-1 is difficult and it is expensive. A slightly tangential
        consideration is using lower grade kerosene which I have seen
        other college students do but I am concerned with using
        low-grade kerosene in regen cooling channels and it obviously
        has poor performance.


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