[AR] Re: Hybrid High Powered Rocket

  • From: Henry Spencer <hspencer@xxxxxxxxxxxxx>
  • To: Arocket List <arocket@xxxxxxxxxxxxx>
  • Date: Mon, 15 Mar 2021 14:48:16 -0400 (EDT)

On Mon, 15 Mar 2021, William Claybaugh wrote:

The Antares launch vehicle uses dozens of Titanium high pressure He tanks *inside* the Lox tank.  Neither that vehicle nor the hundreds of Russian and Soviet heritage designs have ever had a failure caused by the presence of Ti in a Lox bath.

However, quoth ASTM's "Safe Use of Oxygen and Oxygen Systems", 2nd ed., 2014, p. 48:

"Restricted Alloys

"In oxygen systems, the use of certain metals, including titanium, cadmium, beryllium, magnesium, and mercury, must be restricted. Titanium alloys are generally avoided because they exhibit very undesirable flammability and ignition characteristics. Tests have indicated that titanium, α-titanium, and α2-titanium alloys can be ignited and sustain combustion in oxygen at absolute pressures as low as 7 kPa (1 psi). A reaction of titanium and LOX or GOX may propagate and completely consume the metal [11,64–66]. Various titanium alloys tested (α, α−β, β alloys) have shown very high sensitivity to mechanical impact in oxygen [55]. Frictional heating tests conducted on titanium and titanium alloys indicate that the Pv product for ignition is extremely low (Table 3-5). Recent tests indicate that titanium and its alloys also can be ignited in air in frictional heating tests. In addition, titanium particulates are extremely flammable and are exceptional as particle impact ignition sources."

So, not absolutely out of the question, but not generally considered a good idea.

Henry

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