[AR] Re: mixed monoprops (was Re: DARPA responsive launch challenge)

  • From: Henry Spencer <hspencer@xxxxxxxxxxxxx>
  • To: Arocket List <arocket@xxxxxxxxxxxxx>
  • Date: Fri, 27 Apr 2018 13:58:12 -0400 (EDT)

On Fri, 27 Apr 2018, Troy Prideaux wrote:

I can't see acetylene coming out or CO2 for that matter. Nitrous is a very effective solvent for organics. The partnership with something like acetylene will be quite an intimate affair and I just can't see CO2's pacification role producing anything other than a subtle reduction in explosive yield when the 2 energetic compounds inevitably get down and boogie.

Usually you get a non-deliberate explosion not because the whole mass of material got grossly bashed around, but because some tiny localized region got hit hard, e.g. by a gas bubble imploding, and that touched the rest off. Adding inert ingredients *can* increase the heat capacity and reduce the energy yield, per cubic millimeter, enough to make it much harder for localized insults to reach the point of no return; the question is whether you can do it with only modest amounts.

For example, 100% perchloric acid is a lethally touchy explosive, but 70% is safe to handle (or as safe as a ferociously strong acid ever is).

However, finding out how much CO2 you need to pacify N2O/C2H2 adequately would take some effort. Here you wouldn't want to trust a theoretical calculation, even if there is a workable way to do it -- experimental proof is absolutely necessary. It would be a lengthy, noisy, probably expensive process.

Henry

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